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ChemicalBook--->CAS DataBase List--->6651-43-0

6651-43-0

6651-43-0 Structure

6651-43-0 Structure
IdentificationBack Directory
[Name]

1-TRIMETHYLSILOXY-1,3-BUTADIENE
[CAS]

6651-43-0
[Synonyms]

1-TRIMETHYLSILOXY-1,3-BUTADIENE
1-TRIMETHYLSILYLOXY-1,3-BUTADIENE
4-(Trimethylsiloxy)-1,3-butadiene
Trimethyl(1,3-butadienyloxy)silane
(1,3-Butadienyloxy)trimethylsilane
Trimethylsilyl 1,3-butadienyl ether
1,3-Butadienyl(trimethylsilyl) ether
Silane, (1,3-butadienyloxy)trimethyl-
1-(TriMethylsiloxy)-1,3-butadiene 98%
(E)-(buta-1,3-dien-1-yloxy)triMethylsilane
1-(Trimethylsilyloxy)-1,3-butadiene, mixture of isomers, 98%
1-(TRIMETHYLSILYLOXY)-1,3-BUTADIENE, 98% , MIXTURE OF ISOMERS
[Molecular Formula]

C7H14OSi
[MDL Number]

MFCD00009647
[MOL File]

6651-43-0.mol
[Molecular Weight]

142.27
Chemical PropertiesBack Directory
[Appearance]

clear light yellow liquid
[Boiling point ]

131 °C(lit.)
[density ]

0.811 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.448(lit.)
[Fp ]

77 °F
[storage temp. ]

2-8°C
[solubility ]

Sol most standard organic solvents.
[form ]

liquid
[Specific Gravity]

0.811
[Hydrolytic Sensitivity]

7: reacts slowly with moisture/water
[BRN ]

1902024
Hazard InformationBack Directory
[Chemical Properties]

clear light yellow liquid
[Uses]

Diene used in the Diels-Alder reaction.
[Physical properties]

bp 131 °C, bp 49.5 °C/25 mmHg; d 0.811 g cm?3.
[General Description]

Mechanism of Diels-Alder reaction between 1-(trimethylsiloxy)-1,3-butadiene and 4,6-dinitrobenzofuroxan has been studied using state-of-the-art computational methods.
[Purification Methods]

Purify it by fractional distillation and collect the fractions with the required 1H NMR. Store it under N2 — it is a flammable and moisture-sensitive liquid. [Caseau et al. Bull Soc Chim Fr 16658 1972, Belge Patent 670,769, Chem Abstr 65 5487d 1966.]
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

10-36/37/38
[Safety Statements ]

26-36/37/39
[RIDADR ]

UN 1993 3/PG 3
[WGK Germany ]

3
[F ]

10-21
[TSCA ]

No
[HazardClass ]

3.2
[PackingGroup ]

III
Spectrum DetailBack Directory
[Spectrum Detail]

1-TRIMETHYLSILOXY-1,3-BUTADIENE(6651-43-0)1HNMR
1-TRIMETHYLSILOXY-1,3-BUTADIENE(6651-43-0)Raman
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