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ChemicalBook--->CAS DataBase List--->5713-61-1

5713-61-1

5713-61-1 Structure

5713-61-1 Structure
IdentificationBack Directory
[Name]

THIOPHEN-2-YL-MAGNESIUM BROMIDE 1.0M
[CAS]

5713-61-1
[Synonyms]

Bromo-2-thienylmagnesium
2-Thienylmagnesium bromide
magnesium,2H-thiophen-2-ide,bromide
THIOPHEN-2-YL-MAGNESIUM BROMIDE 1.0M
2-Thienylmagnesium bromide solution
thiophen-2-yl-magnesium bromide solution
magnesium bromide thiophen-2-ide (1:1:1)
2-Thienylmagnesium bromide, 1M solution in THF
2-Thienylmagnesium bromide solution 1.0 M in THF
2-Thienylmagnesium bromide, 1M solution in THF, AcroSeal
2-ThienylMagnesiuM broMide, 1.0 M solution in THF, SpcSeal
2-Thienylmagnesium bromide solution, 1.0M in tetrahydrofuran
2-Thienylmagnesium bromide, 1M solution in THF, AcroSeal&trade
[Molecular Formula]

C4H3BrMgS
[MDL Number]

MFCD03094046
[MOL File]

5713-61-1.mol
[Molecular Weight]

187.341
Chemical PropertiesBack Directory
[Boiling point ]

65 °C
[density ]

1.011 g/mL at 25 °C
[Fp ]

−6 °F
[form ]

Solution
[color ]

Yellow to orange to brown
Safety DataBack Directory
[Symbol(GHS) ]


GHS02,GHS07,GHS08
[Signal word ]

Danger
[Hazard statements ]

H225-H302-H319-H335-H351
[Precautionary statements ]

P210-P280-P301+P312+P330-P305+P351+P338-P370+P378-P403+P235
[Hazard Codes ]

F,C,Xn
[Risk Statements ]

11-14-19-22-34-40-36/37
[Safety Statements ]

16-26-36/37/39-45-36/37
[RIDADR ]

UN 2924 3/PG 2
[WGK Germany ]

1
[HS Code ]

29349990
Hazard InformationBack Directory
[Chemical Properties]

Yellow to orange to brown liquid
[Uses]

2-Thienylmagnesium bromide is a Grignard reagent that can be used as a reactant to synthesize:
  • 1-(2-thienyl)-carbinols by condensation reaction with aldehydes. Carbinols are further dehydrated to form 2-thienyl olefins.
  • Thiophene-functionalized polystyrene macromonomer (ThPStM), which is employed as a key intermediate to synthesize polystyrene-graft-polythiophene (PSt-g-PTh) via a combination of atom transfer radical polymerization (ATRP) and Grignard reaction.
  • Thienylene oligomers, which are used as conducting polymers and as potential OLEDs.

[reaction suitability]

reaction type: Grignard Reaction
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