| Identification | Back Directory | [Name]
POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE | [CAS]
54575-49-4 | [Synonyms]
K-selectride
K-SELECTRIDE(R)
insuresealtmbottle
k-selectride solution
K-Selectride(R) solution
(ca. 1.0Mol/L in Tetrahydrofuran)
Potassium tri(s-butyl)borohydride
Potassium tri-sec-butylborohyride
potassium tri-sec-butylhydroborate
POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE
Potassium tris(s-butyl)hydroborate(1-)
Potassium tri-sec-butylhydroborate(1-)
PotassiuM Tri-sec-butylborohydride
Potassium Tri-sec-
Butylborohydride in THF
Potassiumtri-sec-butylborohydride1.0MinTHF
potassium tri-sec-butylborohydride solution
potassiumtri-sec-butylborohydride,calselect?k,
K-SELECTRIDE, 1.0M SOLUTION IN TETRAHYDR OFURAN
potassium,(beta-4)-borate(1-hydrotris(1-methylpropyl)-
POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE SOLUT ION, 1 M IN THF
Borate(1-), hydrotris(1-methylpropyl)-, potassium, (T-4)-
Potassiumtri-sec-butylborohydride,1.0MinTHF,inSure/Sealbottle
potassiumtri-sec-butylborohydride,calselect?k,intetrahydrofuran
Potassium tri-sec-butylborohydride, in tetrahydrofuran, 1M solution
Potassium tri-sec-butylborohydride, 1 M solution in tetrahydrofuran
Potassium Tri-sec-butylborohydride (ca. 1.0mol/L in Tetrahydrofuran)
POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE, 1.0M IN THF, IN SURE/SEAL TM BOTTLE
K-Selectride(R) solution 1.0 M potassiuM tri-sec-butylborohydride in THF
Potassium tri-sec-butylborohydride1M solution in tetrahydrofuranAcroSeal§3
Potassium tri-sec-butylborohydride, 1M solution in tetrahydrofuran, AcroSeal | [EINECS(EC#)]
259-241-7 | [Molecular Formula]
C12H28BK | [MDL Number]
MFCD00009324 | [MOL File]
54575-49-4.mol | [Molecular Weight]
222.26 |
| Hazard Information | Back Directory | [Chemical Properties]
clear slightly yellow solution | [Uses]
Reducing reagent. Reactant for: Preparation of a PCP-pincer palladium hydride-K-Selectride complex. Formation of P-H, P-C, and C-H bonds by hydride attack. Stereoselective conjugate hydride reduction reactions. | [Uses]
Mild reducing agents in organic synthesis. | [Description]
Potassium tri-sec-butylborohydride [54575- 49-4] solution in tetrahydrofuran (THF) is sold as K-Selectride (Aldrich). These compounds may be used for highly stereoselective reductions, e.g., of ketones . Chemical rearrangements induced by potassium hydride are important in organic chemistry. Furthermore, in combination with other reagents potassium hydride acts as a catalyst in the polymerization of alkenes and dienes. | [reaction suitability]
reagent type: reductant |
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