| Identification | Back Directory | [Name]
4-Methylnaphthalen-1-aMine | [CAS]
4523-45-9 | [Synonyms]
4-Methylnaphthalen-1-aMine
4-methyl-1-Naphthalenamine
1-Naphthalenamine, 4-methyl-
4-Methyl-naphthalen-1-ylamine | [Molecular Formula]
C11H11N | [MDL Number]
MFCD01171821 | [MOL File]
4523-45-9.mol | [Molecular Weight]
157.21 |
| Chemical Properties | Back Directory | [Melting point ]
51.5°C | [Boiling point ]
271.88°C (rough estimate) | [density ]
1.0595 (rough estimate) | [refractive index ]
1.6722 (estimate) | [storage temp. ]
Keep in dark place,Sealed in dry,Room Temperature | [pka]
4.63±0.10(Predicted) |
| Hazard Information | Back Directory | [Synthesis]
General procedure for the synthesis of 4-methylnaphthalen-1-amine from 1-methyl-4-nitronaphthalene: To a solution of 1-methyl-4-nitronaphthalene (4.0 g, 21 mmol) in ethanol (300 mL) was added Raney-Ni (about 4 scoops). The reaction mixture was stirred under hydrogen (1 atm) atmosphere for 16 hours. Upon completion of the reaction, the catalyst was removed by filtration through a diatomaceous earth pad and the filtrate was concentrated. Finally, the target product 4-methylnaphthalen-1-amine (3.2 g, 75% yield) was purified by silica gel fast column chromatography (eluent ratio ethyl acetate:hexane = 15:85). | [References]
[1] Chinese Journal of Chemistry, 2017, vol. 35, # 10, p. 1595 - 1600
[2] Journal of Polymer Science, Part A: Polymer Chemistry, 2011, vol. 49, # 3, p. 719 - 728
[3] Patent: WO2006/26356, 2006, A2. Location in patent: Page/Page column 42
[4] Justus Liebigs Annalen der Chemie, 1913, vol. 402, p. 28
[5] Zhurnal Prikladnoi Khimii (Sankt-Peterburg, Russian Federation), 1955, vol. 28, p. 115,117; engl. Ausg. S. 109 |
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SynAsst Chemical.
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Cool Pharm, Ltd
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