| Identification | Back Directory | [Name]
TRIMETHYLENE DI(THIOTOSYLATE) | [CAS]
3866-79-3 | [Synonyms]
NSC 82472
1,3-DI(P-TOSYLTHIO)PROPANE
TRIMETHYLENE DI(THIOTOSYLATE)
1,3-Propanedithiol ditosylate
1,3-PROPANEDIYL DI(THIOTOSYLATE)
1,3-Propanediylbis(tosyl sulfide)
1,3-bis(p-toluenesulfonylthio)propane
Trimethylene di-p-toluenethiosulfonate
TRIMETHYLENE BIS(P-TOLUENETHIOSULFONATE)
1,3-Propanedithiolebis(p-toluenesulfonate)
1,3-Bis(4-methylbenzenesulfonylthio)propane
S,S'-Trimethylene di(p-toluenethiosulfonate)
4-Methylbenzenesulfonothioic acid S1,S1'-1,3-propanediyl ester
Benzenesulfonothioic acid, 4-methyl-, S,S-1,3-propanediyl ester
Benzenesulfonothioicacid, 4-methyl-, S1,S1'-1,3-propanediyl ester
TrimethyleneDi(thiotosylate)[ProtectingReagentforActiveMethylene]>
1-methyl-4-[3-[(4-methylphenyl)sulfonylthio]propylthio]sulfonyl-benzene
Trimethylene Di(thiotosylate) [Protecting Reagent for Active Methylene]
p-Toluenesulfonothioic acid S-[3-[(4-methylphenyl)sulfonylthio]propyl] ester
1-methyl-4-[3-(4-methylphenyl)sulfonylsulfanylpropylsulfanylsulfonyl]benzene
1,3-Di(p-tosylthio)propane, 1,3-Propanediyl di(thiotosylate), Trimethylene di(thiotosylate)
1,3-Di(p-tosylthio)propane
1,3-Propanediyl Di(thiotosylate)
Trimethylene Bis(p-toluenethiosulfonate) | [Molecular Formula]
C17H20O4S4 | [MDL Number]
MFCD00014918 | [MOL File]
3866-79-3.mol | [Molecular Weight]
416.6 |
| Chemical Properties | Back Directory | [Melting point ]
64-67 °C
| [Boiling point ]
592.3±60.0 °C(Predicted) | [density ]
1.340±0.06 g/cm3(Predicted) | [form ]
powder to crystal | [color ]
White to Almost white | [BRN ]
2020157 | [CAS DataBase Reference]
3866-79-3 |
| Hazard Information | Back Directory | [Uses]
Trimethylene Di(thiotosylate) is used as a reactant in the enantioselective total synthesis of (-)-O-methylpallidinine, which is a naturally occurring morphinan alkaloid. | [Reactions]
1,3-Propanedithiol Bis(p-toluenesulfonate) could be used in the below reactions:
dithianylation and dithiolanylation of methylene groups adjacent to carbonyl; α,α-dithianyl cycloalkanones undergo oxidative ring scission; oxidation of ketones to 1,2-diketones can be achieved by α,α-dithianylation or dithiolanation of ketones followed by hydrolysis.
| [Synthesis]
Treatment of potassium thiotosylate, itself made by the reaction of p-Toluenesulfonyl Chloride with Potassium Hydrogen Sulfide, with 1,3-dibromopropane or 1,2-dibromoethane in the presence of Potassium Iodide affords 1,3-propanedithiol bis(p-toluenesulfonate) and 1,2-ethanedithiol bis(p-toluenesulfonate), respectively. |
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