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ChemicalBook--->CAS DataBase List--->220114-38-5

220114-38-5

220114-38-5 Structure

220114-38-5 Structure
IdentificationBack Directory
[Name]

Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II)
[CAS]

220114-38-5
[Synonyms]

DM−
BINAP][(R,R)−
Dichloro{(R)-(+)-2,2'
RuCl2[(R)−
RuCl2[(R)-DM-BINAP][(R,R)-DPEN]
RuCl2[(R)-xylbinap][(R,R)-dpen]
-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II),RuCl2[(
Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II)
Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(R)-xylbinap][(R,R)-dpen]
[Molecular Formula]

C66H64Cl2N2P2Ru
[MDL Number]

MFCD09753028
[MOL File]

220114-38-5.mol
[Molecular Weight]

1119.17
Chemical PropertiesBack Directory
[storage temp. ]

2-8°C
[form ]

Powder
[color ]

yellow
[Sensitive ]

air sensitive
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H319-H335-H315
[Precautionary statements ]

P264-P280-P305+P351+P338-P337+P313P-P264-P280-P302+P352-P321-P332+P313-P362
[WGK Germany ]

3
[HS Code ]

2843.90.0000
Hazard InformationBack Directory
[Uses]

RuCl2[(R)-DM-BINAP][(R,R)-DPEN] can catalyze the enantioselective asymmetric reduction of benzils to form the corresponding chiral 1,2-diols.
[General Description]

The product is a bis-naphthalene containing phosphine ligand, in conjugation with a ruthenium complex.
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