| Identification | Back Directory | [Name]
Ir[dFFppy]2-(4,4'-dCF3bpy)PF6 | [CAS]
2030437-92-2 | [Synonyms]
Ir[dFFppy]2-(4,4'-dCF3bpy)PF6
IR [DFFPPY] 2-(4,4'- DCF3BPY)PF6 | [Molecular Formula]
C34H16F18IrN4P | [MDL Number]
MFCD27952560 | [MOL File]
2030437-92-2.mol | [Molecular Weight]
1045.69 |
| Hazard Information | Back Directory | [Uses]
Under a dual catalytic copper/photoredox manifold, the Mes-Umemoto reagent has been demonstrated to be an excellent photocatalyst for the trifluoromethylation of alkyl halides and aryl halides to yield alkyl-CF3 and aryl-CF3 in high yields. In both cases, these reactions exhibit wide substrate scope with good functional group tolerance. More specifically, a variety of 5-membered and 6-membered heteroaryl halides can be readily converted to the corresponding trifluoromethylheteroarenes under mild conditions. For trifluoromethylation reactions, use with dMesSCF3 (901466) and supersilanol (902489). | [reaction suitability]
core: iridium
reagent type: catalyst
reaction type: Photocatalysis |
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