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ChemicalBook--->CAS DataBase List--->147702-16-7

147702-16-7

147702-16-7 Structure

147702-16-7 Structure
IdentificationBack Directory
[Name]

(R)-VAPOL
[CAS]

147702-16-7
[Synonyms]

(R)-VAPOL
(S)-VAPOL
(R)-VAPOL 97%
(R)-VAPOL,99%e.e.
(S)-2,2'-DIPHENYL-(4-BIPHENANTHROL)
(R)-2,2'-DIPHENYL-3,3'-(4-BIPHENANTHROL)
(R) -2,2'--diphenyl-3,3 '- (4-phenanthrenol
(3R)-(-)-2,2'-DIPHENYL-[3,3'-BIPHENANTHRENE]-4,4'-DIOL DICHLOROMETHANE ADDUCT
(3S)-(+)-2,2'-DIPHENYL-[3,3'-BIPHENANTHRENE]-4,4'-DIOL DICHLOROMETHANE ADDUCT
(3R)-(-)-2,2''-DIPHENYL-[3,3''-BIPHENANTHRENE]-4,4''-DIOL DICHLOROMETHANE ADDUCT (R)-VAPOL
(3R)-(-)-2,2'-Diphenyl-[3,3'-biphenanthrene]-4,4'-dioldichloromethaneadduct,min.98%(R)-VAPOL
[Molecular Formula]

C40H26O2
[MDL Number]

MFCD08459339
[MOL File]

147702-16-7.mol
[Molecular Weight]

538.64
Chemical PropertiesBack Directory
[Melting point ]

225-229 °C
[alpha ]

-123.4° (c 1.0, THF)
[Boiling point ]

712.2±60.0 °C(Predicted)
[density ]

1.286±0.06 g/cm3(Predicted)
[storage temp. ]

under inert gas (nitrogen or Argon) at 2–8 °C
[form ]

Powder
[pka]

8.37±0.30(Predicted)
[color ]

white to pale yellow
[optical activity]

[α]20/D -144°, c = 1 in chloroform
Safety DataBack Directory
[Symbol(GHS) ]


GHS05,GHS07,GHS08
[Signal word ]

Danger
[Hazard statements ]

H315-H318-H335-H351
[Precautionary statements ]

P201-P202-P280-P302+P352-P305+P351+P338-P308+P313
[Hazard Codes ]

Xn
[Risk Statements ]

37/38-40-41
[Safety Statements ]

26-36/37/39
[WGK Germany ]

3
Questions And AnswerBack Directory
[Reaction]

  1. Chiral ligand used in catalytic asymmetric aziridination.
  2. Chiral ligand used in catalytic asymmetric imino aldol reaction.
  3. Chiral ligand used in catalytic asymmetric Petasis reaction. 
Reactions of 147702-16-7
Hazard InformationBack Directory
[Uses]

VAPOL has proven to be an excellent ligand in catalytic asymmetric Diels-Alder, imine aldol, and aziridination reactions.
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