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ChemicalBook--->CAS DataBase List--->1384974-37-1

1384974-37-1

1384974-37-1 Structure

1384974-37-1 Structure
IdentificationBack Directory
[Name]

N-[(1S,2S)-1,2-Diphenyl-2-(2-(4-Methylbenzyloxy)ethylaMino)-ethyl]-4-Methylbenzene sulfonaMide(chloro)rutheniuM(II) (S,S)-Ts-DENEB
[CAS]

1384974-37-1
[Synonyms]

(S,S)-Ts-DENEB[R]
(S,S)-Ts-DENEB®
(S,S)-Ts-DENEB(regR)
N-[(1S,2S)-1,2-Diphenyl-2-(2-(4-Methylbenzyloxy)ethylaMino)-ethyl]-4-Methylbenzene sulfonaMide(chloro)rutheniuM(II) (S,S)-Ts-DENEB
N-[(1S,2S)-1,2-Diphenyl-2-(2-(4-methylbenzyloxy)ethylamino)-ethyl]-4-methylbenzene sulfonamide(chloro)ruthenium(II) (S,S)-Ts-DENEB(TM)
[Molecular Formula]

C31H33ClN2O3RuS
[MDL Number]

MFCD22666040
[MOL File]

1384974-37-1.mol
[Molecular Weight]

645.16
Chemical PropertiesBack Directory
[form ]

solid
[color ]

gray to brown
[Sensitive ]

air sensitive
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319
[Precautionary statements ]

P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313
[RIDADR ]

UN 3077 9/PG III
[HS Code ]

2843.90.0000
[HazardClass ]

9
[PackingGroup ]

III
Questions And AnswerBack Directory
[Reaction]

1. Catalyst used for asymmetric -transfer hydrogenation. Reactions of 1384974-37-1_1 2. Catalyst used for asymmetric H2 – hydrogenation. Reactions of 1384974-37-1_2 3. Catalyst used for dynamic kinetic resolution. Reactions of 1384974-37-1_3
Hazard InformationBack Directory
[Uses]

(S,S)-Ts-DENEB (regR) (CAS# 1384974-37-1) is a catalyst used in transfer hydrogenation reactions, such as in the selective asymmetric transfer hydrogenation of α-substituted acetophenones, and asymmetric transfer hydrogenation of aryl N-heteroaryl ketones.
[reaction suitability]

reagent type: ligand
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