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ChemicalBook--->CAS DataBase List--->1375325-77-1

1375325-77-1

1375325-77-1 Structure

1375325-77-1 Structure
IdentificationBack Directory
[Name]

XantPhos-Pd-G2
[CAS]

1375325-77-1
[Synonyms]

XantPhos Pd G2
Xantphos Palladacycle Gen.2
Chloro[(4,5-bis(diphenylphosphino)-9,9-diMethylxanthene)-2-(2'-aMino-1,1'-bipheny
Chloro[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene][2'-amino-1,1'-biphenyl]palladium(II)
Chloro[(4,5-bis(diphenylphosphino)-9,9-dimethylxanthene)(2-amino-1,1-biphenyl-2-yl)palladium(II)
Chloro[(4,5-bis(diphenylphosphino)-9,9-diMethylxanthene)-2-(2'-aMino-1,1'-biphenyl)]palladiuM(II)
Chloro[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene][2'-amino-1,1'-biphenyl]palladium(II),XantPhos Pd G2
Chloro[(4,5-bis(diphenylphosphino)-9,9-dimethylxanthene)(2-amino-1,1-biphenyl-2-yl)palladium(II) / XantPhos Pd G2
Chloro[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene][2'-amino-1,1'-biphenyl]palladium(II) dichloromethane adduct
[2'-(Amino)[1,1'-biphenyl]-2-yl]chloro[[5-(diphenylphosphino)-9,9-dimethyl-9H-xanthen-4-yl]diphenylphosphine]palladium
Chloro[9,9-diMethyl-4,5-bis(diphenylphosphino)xanthene][2'-aMino-1,1'-biphenyl]palladiuM(II) dichloroMethane adduct, Min. 98%
Palladium, [2'-(amino-κN)[1,1'-biphenyl]-2-yl-κC]chloro[[5-(diphenylphosphino)-9,9-dimethyl-9H-xanthen-4-yl]diphenylphosphine-κP]-
CHLORO[9,9-DIMETHYL-4,5-BIS(DIPHENYLPHOSPHINO)XANTHENE][2'-AMINO-1,1'-BIPHENYL]PALLADIUM(II)DICHLOROMETHANEADDUCT,MIN.98%[XANTPHOSPALLADACYCLEGEN.2]
[Molecular Formula]

C51H41ClNOP2Pd+2
[MDL Number]

MFCD22666442
[MOL File]

1375325-77-1.mol
[Molecular Weight]

887.698
Chemical PropertiesBack Directory
[Melting point ]

188-196 (decomposition)
[storage temp. ]

Inert atmosphere,2-8°C
[form ]

Powder
[color ]

pale yellow
[InChIKey]

WBWMRHAPSXPODD-UHFFFAOYSA-N
[SMILES]

P(C1C=CC=CC=1)(C1C=CC=CC=1)(C1C=CC=C2C(C3=CC=CC(P(C4C=CC=CC=4)C4C=CC=CC=4)=C3OC=12)(C)C)[Pd+2]1(NC2=CC=CC=C2C2=CC=CC=[C-]12)[Cl-]
Safety DataBack Directory
[WGK Germany ]

3
[HS Code ]

2931499090
Hazard InformationBack Directory
[Description]

XantPhos-Pd-G2 is an inhibitor of palladium-catalyzed cross-coupling reactions. It is stable, and can be used as a catalyst for the cross-coupling of a variety of activated, metalated organic compounds with alkyl halides.
[Uses]

XantPhos-Pd-G2 is a second generation palladium precatalyst with improved reactivity in palladium-catalyzed C-N cross-coupling reactions.
[Application]

XantPhos-Pd-G2 is used to synthesize various pharmaceuticals, including antihypertensive drugs and antibiotics.
[reaction suitability]

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: Cross Couplings
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