| Identification | Back Directory | [Name]
Vinylferrocene | [CAS]
1271-51-8 | [Synonyms]
VINYLFERROCENE
Vinylferrocene,99%
Vinylferrocene,98%
Vinylferrocene 97%
Ferrocene, ethenyl-
Vinylferrocene ,97%
Vinylferroceneorangextl
Vinylferrocene**CUSTOMSYNTHESISPLEASEASK** | [EINECS(EC#)]
215-041-1 | [Molecular Formula]
C12H12Fe 10* | [MDL Number]
MFCD00001434 | [MOL File]
1271-51-8.mol | [Molecular Weight]
212.07 |
| Chemical Properties | Back Directory | [Appearance]
crystalline solid | [Melting point ]
51-53 °C(lit.)
| [Boiling point ]
80-85 °C0.2 mm Hg(lit.)
| [Fp ]
144 °F
| [storage temp. ]
2-8°C
| [form ]
crystal | [color ]
orange | [Stability:]
Stable. Highly flammable. Incompatible with strong acids, strong oxidizing agents. | [Water Solubility ]
Insoluble in water. | [Hydrolytic Sensitivity]
4: no reaction with water under neutral conditions | [Exposure limits]
ACGIH: TWA 1 mg/m3
NIOSH: TWA 1 mg/m3 | [NIST Chemistry Reference]
Vinylferrocene(1271-51-8) |
| Hazard Information | Back Directory | [Chemical Properties]
crystalline solid | [Definition]
ChEBI: Ferrocene substituted on one of the cyclopentadienyl rings by a vinyl group. | [Uses]
Used in the synthesis of 2-aminomethylferrocenes from vinyl ferrocene and lithium amides. | [reaction suitability]
core: iron
reagent type: catalyst | [Purification Methods]
Dissolve vinylferrocene in Et2O, wash it with H2O and brine, dry (Na2SO4), and evaporate to a small volume. Purify it through an Al2O3 (Spence grade H) column by eluting the yellow band with pet ether (b 40-60o). The low melting orange crystals can be sublimed. The tetracyanoethylene adduct crystallises from *C6H6/pentane and has m 137-139o(dec). [Horspool & Sutherland Can J Chem 46 3453 1968, Berger et al. J Org Chem 39 377 1974, Rauch & Siegel J Organomet Chem 11 317 1968, Beilstein 16 III 1787.] |
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