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ChemicalBook--->CAS DataBase List--->1231763-32-8

1231763-32-8

1231763-32-8 Structure

1231763-32-8 Structure
IdentificationBack Directory
[Name]

9-Amino-(9-deoxy)epi-quinine trihydrochloride
[CAS]

1231763-32-8
[Synonyms]

(8α,9S)-6′-Methoxycinchonan-9-amine trihydrochloride
(8alpha,9S)-6'-Methoxycinchonan-9-amine trihydrochloride >=90%
(8α, 9S)-6'-Methoxycinchonan-9-amine trihydrochloride, min. 90%
(S)-{5-Ethenyl-1-azabicyclo[2.2.2]octan-2-yl}-(6-methoxyquinolin-4-yl)methanamine trihydrochlo
[Molecular Formula]

C20H25N3O·3HCl
[MDL Number]

MFCD22666022
[MOL File]

1231763-32-8.mol
[Molecular Weight]

432.815
Chemical PropertiesBack Directory
[alpha ]

+59.4° (c=1.0, H2O)
[form ]

Powder
[color ]

pale yellow
[optical activity]

[α]/D +65.0±2.0°, c = 1 in 0.1 M HCl
[Stability:]

store cold
Hazard InformationBack Directory
[Chemical Properties]

Solid
Safety DataBack Directory
[Symbol(GHS) ]


GHS06
[Signal word ]

Danger
[Hazard statements ]

H301
[Precautionary statements ]

P264-P270-P301+P310+P330-P405-P501
[Hazard Codes ]

T
[Risk Statements ]

25
[Safety Statements ]

45
[RIDADR ]

UN 2811 6.1 / PGIII
[WGK Germany ]

3
[HS Code ]

29339900
Questions And AnswerBack Directory
[Reaction]

  1. Aza-Michael reactions on α,β-unsaturated ketones.
  2. Epoxidation of α,β-unsaturated ketones.
  3. Epoxidation of α,β-unsaturated aldehydes.
  4. Nitrocyclopropanation of α,β-unsaturated ketones.
  5. Diels-Alder reaction.
  6. Intramolecular aldolization of diketones.
  7. Friedel-Crafts alkylation of indoles with α,β-unsaturated ketones.
  8. Friedel-Crafts/amination cascade reactions with a-substituted α,β-unsaturated aldehydes.
  9. Aziridination of acyclic α,β-unsaturated ketones.
  10. Aziridination of cyclic α,β-unsaturated ketones.
  11. Double Michael cascade process.
  12. α-fluorination of cyclic ketones. 
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