| Identification | Back Directory | [Name]
BENZENE CHROMIUM TRICARBONYL | [CAS]
12082-08-5 | [Synonyms]
Benchrotrene
Benzenechromotricarbonyl
Benzentrikarbonylchromium
tricarbonylbenzenechromium
Tricarbonylbenzene chromium
BENZENE CHROMIUM TRICARBONYL
CHROMIUM BENZENE TRICARBONYL
(BENZENE)TRICARBONYLCHROMIUM
(benzene)tricarbonyl-chromiu
pi-benzenechromiumtricarbonyl
pi-Benzenetricarbonylchromium
(6-Benzene)tricarbonylchromium
pi-Benzenechromium tricarbonyl
Benzenechromiumtricarbonyl,98%
benzene-chromium(0) tricarbonyl
(η6-benzene)tricarbonylchromium
eta6-Benzenetricarbonylchromium
(BENZENE)TRICARBONYLCHROMIUM(0)
(BENZENE)TRICARBONYLCHROMIUM,98%
BENZENE CHROMIUM TRICARBONYL 98%
Benzene-chromium carbonyl complex
Benzene-chromium(0) tricarbonyl 98%
eta(sup6)-Benzenetricarbonylchromium
Benzene chroMiuM tricarbonyl, 98% 1GR
(eta(sup6)-benzene)tricarbonyl-chromiu
Chromium,(mu6-benzene)tricarbonyl- | [EINECS(EC#)]
235-146-6 | [Molecular Formula]
C9H6CrO3 6* | [MDL Number]
MFCD00009955 | [MOL File]
12082-08-5.mol | [Molecular Weight]
214.14 |
| Hazard Information | Back Directory | [Chemical Properties]
yellow crystalline powder | [Uses]
Catalyst for:
- Oxidation of alkenes
- Hydrogenation of alkynes
| [Preparation]
For cases where large quantities are needed, benzene chromium tricarbonyl is easily prepared from the reaction of benzene with Hexacarbonylchromium.
| [reaction suitability]
core: chromium
reagent type: catalyst | [Solubility in organics]
benzene chromium tricarbonyl is soluble in THF, ether, benzene.
| [Purification Methods]
Purify the complex by sublimation in vacuo. A possible impurity is 2-picoline which can be removed by washing with pentane and drying. It is then purified further by sublimation at 80-85o/10-3mm, or by recrystallisation from Et2O to give yellow crystals. 1H NMR in CDCl3 should give a single peak at 4.68. [Rausch J Org Chem 39 1787 1974, Pauson in Houben-Weyl Meth Org Chem V, E 18 Pt I p226 Theme Verlag, Stuttgart 1986, Beilstein 5 IV 625.] |
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Sigma-Aldrich
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