| Identification | Back Directory | [Name]
[Ir{dFCF3ppy}2(bpy)]PF6 | [CAS]
1092775-62-6 | [Synonyms]
[Ir{dFCF3ppy}2(bpy)]PF6
Bis [2- (2,4-difluorophenyl) -5-trifluoromethylpyridine] [2-2'-bipyridyl] iridium hexafluorophosphate | [Molecular Formula]
C34H18F16IrN4P | [MOL File]
1092775-62-6.mol | [Molecular Weight]
1009.7 |
| Chemical Properties | Back Directory | [storage temp. ]
Keep in dark place,Inert atmosphere,Room temperature | [form ]
Powder | [color ]
yellow | [Sensitive ]
air sensitive | [InChIKey]
ZCNUFCYLERNPGN-UHFFFAOYSA-N |
| Questions And Answer | Back Directory | [Reaction]
- Catalyst used for the chemo-, regio, and stereoselective trifluoromethylation of styrene.
- Photoredox catalyst used in cross-coupling: Ir/Ni dual catalysts for the synthesis of benzylic ethers.
- Iridium complex used for catalytic olefin hydroamidation enabled by proton-coupled electron transfer.
- Catalyst used for visible light photoredox cross-coupling of acyl chlorides with potassium alkoxymethyltrifluoroborates.
- Iridium catalyst used in the photoredox/nickel dual catalytic cross-coupling of secondary alkyl β-trifluoroboratoketones and –esters with aryl bromides.
- Photocatalyst used in the cross-coupling of trifluoroalkylboranes.
|
| Hazard Information | Back Directory | [Uses]
When used in tandem with a nickel catalyst, the above photoredox catalyst effects the cross-coupling of C-sp3 hybridized trifluoroborates with aryl bromides under exceptionally mild conditions. | [reaction suitability]
core: iridium
reagent type: catalyst
reaction type: Photocatalysis |
|
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TCI Europe
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TCI AMERICA
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