| Identification | Back Directory | [Name]
Chlorodi(p-tolyl)phosphine, 95% | [CAS]
1019-71-2 | [Synonyms]
orodi(p-toL
Di-p-tolylchlorophosphine
chlorodi-p-tolylphosphane
Chlorodi(p-tolyl)phosphine, 95%
Di(p-tolyl)phosphinous Chloride
Chlorodi(p-tolyl)phosphine
Chlorobis(4-methylphenyl)phosphine
chloro-bis(4-methylphenyl)phosphane
Phosphinous chloride, P,P-bis(4-methylphenyl)-
P,P-Bis(4-methylphenyl)-phosphinous chloride, Chlorodi-p-tolylphosphine | [EINECS(EC#)]
202-848-9 | [Molecular Formula]
C14H14ClP | [MDL Number]
MFCD01630844 | [MOL File]
1019-71-2.mol | [Molecular Weight]
248.69 |
| Chemical Properties | Back Directory | [Boiling point ]
180-184℃/10mm | [density ]
1.1 g/mL at 25 °C | [refractive index ]
n20/D1.501 | [storage temp. ]
Sealed in dry,2-8°C | [form ]
liquid | [Water Solubility ]
Reacts with water. | [Sensitive ]
Air & Moisture Sensitive |
| Hazard Information | Back Directory | [Uses]
Reactant for synthesis of:
- Palladium catalysts for C-C bond forming cross-coupling reactions
- Ligands for nickel(0)-catalyzed isomerization reactions
- Phosphinosulfonamide nickel complexes for oligomerization reactions
Reactant for:
- Pd-catalyzed intramolecular asymmetric allylic amination and ring-closing metathesis
- Phosphinylation reactions
| [Uses]
Chlorodi(p-tolyl)phosphine is used as a reactant for synthesis of palladium catalysts for C-C bond forming cross-coupling reactions, ligands for nickel(0)-catalyzed isomerization reactions, phosphinosulfonamide nickel complexes for oligomerization reactions. It is a reactant for phosphinylation reactions. | [reaction suitability]
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand |
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